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Thermodynamics of liquid Al-In, Ag-In and In-Sb alloys from a four-atom cluster model

Identifieur interne : 00C921 ( Main/Repository ); précédent : 00C920; suivant : 00C922

Thermodynamics of liquid Al-In, Ag-In and In-Sb alloys from a four-atom cluster model

Auteurs : RBID : Pascal:04-0054949

Descripteurs français

Pascal (Inist)
- Propriété thermodynamique, Alliage liquide, Système binaire, Modélisation, Fonction thermodynamique, Etude théorique, Aluminium alliage, Indium alliage, Argent alliage, Antimoine alliage, 6540G.

English descriptors

KwdEn :
- Aluminium alloys, Antimony alloys, Binary systems, Indium alloys, Liquid alloys, Modelling, Silver alloys, Theoretical study, Thermodynamic function, Thermodynamic properties.

Abstract

A model based on a cluster of four atoms has been used to obtain higher-order conditional probabilities that describe the atomic correlations in Al-In, Ag-In and In-Sb liquid alloys. Using the value of the ordering energy obtained from the model, some thermodynamic quantities such as Gibbs energy of mixing and concentration-concentration fluctuations in the long wavelength limit were calculated for these alloys. Our study of the energetics of these liquid alloys reveals that while In-Sb and Ag-In are both chemically ordered or heterocoordinated systems, Al-In is a segregating system. Furthermore, the degree of order in liquid In-Sb alloys is higher than that in liquid Ag-In alloys.

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Pascal:04-0054949

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<front><div type="abstract" xml:lang="en">A model based on a cluster of four atoms has been used to obtain higher-order conditional probabilities that describe the atomic correlations in Al-In, Ag-In and In-Sb liquid alloys. Using the value of the ordering energy obtained from the model, some thermodynamic quantities such as Gibbs energy of mixing and concentration-concentration fluctuations in the long wavelength limit were calculated for these alloys. Our study of the energetics of these liquid alloys reveals that while In-Sb and Ag-In are both chemically ordered or heterocoordinated systems, Al-In is a segregating system. Furthermore, the degree of order in liquid In-Sb alloys is higher than that in liquid Ag-In alloys.</div>
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Thermodynamics of liquid Al-In, Ag-In and In-Sb alloys from a four-atom cluster model

Thermodynamics of liquid Al-In, Ag-In and In-Sb alloys from a four-atom cluster model

Descripteurs français

English descriptors

Abstract

Links toward previous steps (curation, corpus...)

Links to Exploration step

Le document en format XML

Pour manipuler ce document sous Unix (Dilib)

Pour mettre un lien sur cette page dans le réseau Wicri